Here is an interesting article called
The $5 trillion mistakeIt's by Rogelio A. Maduro and Bob HolzknechtIt was published in Machine Design on Jan. 24, 1994It's pretty much about how the ban or freon, CFCs and chlorofluorocarbons is junk science. Here is a summary of the article: The global ban on chlorofluorocarbons (CFCs) will cost governments and consumers a total of $5 trillion. The scientific community does not have a general consensus on CFCs, and the effects of the ban on humans, society and industry have not been fully considered. Industrial processes are undergoing radical changes, with engineers redesigning machinery and processes to replace supposed ozone-depleting refrigerants, solvents and fire-fighting agents. Increased prices, a lower standard of living and no significant improvement in the environment make people wonder if the benefits are worth the cost.
The $5 trillion mistakeRogelio A. Maduro and Bob Holzknecht,/h4>
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Covering the teleconference, Air Conditioning, Heating and Refrigeration News reported: "The sheer numbers of CFC-bearing equipment eligible for conversion or replacement to . . . alternatives are mind-boggling. And, if you divide the number of existing chillers--specifically, the amount of refrigerant they require--by the amount of CFCs available, the numbers can seem downright intimidating. The General Services Administration (GSA) . . . has 650 to 675 chillers cooling 300 million |ft.sup.2~ of office space. It is expected to cost $100 million per year to either replace, retrofit, or contain the refrigerant within them over the next three to five years." There are no studies of the national cost of replacing or retrofitting all of these chillers. However, extrapolating the GSA figures shows that the total cost will exceed $10 billion per year in the U.S. Unfortunately, this calamity does not end with retrofits or new units. A large percentage the of new units and retrofits use HCFC-123 as the refrigerant. These chillers require the installation of several refrigerant sensors and alarms to ensure that the building can be quickly evacuated in case the system springs a leak. In addition, building codes may force extensive reconstruction to house chillers in rooms separate from the boilers, with each room having its own independent ventilation system. That's necessary because HCFC-123 turns into a poisonous gas when exposed to an open flame. Dangerous substitutes Not only will getting rid of current CFC-based equipment be expensive, the replacements currently available are dangerous and inefficient. Choosing those replacements has also been controversial. One of the most arbitrary and capricious acts in the CFC ban saga has been the method by which CFC substitutes have been chosen. The EPA has set up a committee that decides which chemicals are allowed to become CFC substitutes. This committee rejected several alternatives to CFCs, mandating the patented HFC-134a as the only replacement allowed for auto air conditioners. There are several major problems with HFC-134a, including the fact that it is an unsuitable replacement for existing CFC-12-based refrigeration/air conditioning systems. HFC-134a also is already being targeted by Greenpeace and EPA for phaseout as a harmful "greenhouse gas." In addition, there isn't enough manufacturing capacity available to have enough HFC-134a on hand five years earlier than previously planned. Safety is another problem. CFCs have an unparalleled safety record covering their 50 years. They are useful, efficient, effective, cheap, nontoxic, nonflammable, noncarcinogenic, nonexplosive, noncorrosive, do not damage fabrics or other materials, and do not deteriorate in storage. Just the opposite can be said of CFC substitutes. They are new and experimental. They have not existed long enough for any conclusive long-range testing. Already they are known to suffer from one, or several, of the following problems: corrosiveness, toxicity, carcinogenesis, combustibility, energy inefficiency, and long-term instability. Furthermore, they require new lubricants and desiccants, and they are very expensive. DuPont's SUVA family of chemicals, the brand name for the most abundant CFC replacement chemicals now on the market, are very dangerous, according to the industry itself. A DuPont service bulletin, "Safety of SUVA Refrigerants (AS-1)," warns: "Inhaling high concentrations of SUVA refrigerant vapor may cause temporary central nervous system depression with narcosis, lethargy, and anesthetic effects . . . dizziness, a feeling of intoxication, and a loss of coordination. Continued breathing of high concentrations of SUVA vapor may produce cardiac irregularities, unconsciousness, and with gross overexposure, death." High concentrations, according to DuPont, are 30 parts per million for HCFC-123 (SUVA Centri-LP) and 1,000 ppm for HFC-134a (SUVA Trans A/C), over a period of 8 hours. Anyone who works with refrigerants knows that it is nearly impossible not to encounter these and much higher concentrations during air conditioning and refrigeration work. Discussing SUVA's combustible and explosive qualities, DuPont reports that HFC-134a has been shown in tests to be combustible at pressures as low as 5.5 psig at 350 |degrees~ F when mixed with air. "SUVA refrigerants should not be mixed with air for leak testing. In general, they should not be used or allowed to be present with high concentrations of air above atmospheric pressure," the bulletin advises. This warning might come too late for some service personnel since leaky automobile air conditioners always contain infiltrated air, even before the leak testing begins. The bulletin also warns that cylinders containing SUVA can explode at temperatures above 257 |degrees~ F. It does not discuss what happens to SUVA in engine compartments where underhood temperatures commonly reach 300 |degrees~ F. Exploding cylinders are not the only threat. "SUVA refrigerants will decompose when exposed to high temperatures from flames or electric resistance heaters. Decomposition may produce toxic . . . compounds," DuPont says. The fact that most household refrigerators are located next to the gas or electric range makes this danger even more obvious. Although more people will be exposed to HFC-134a than to any other CFC replacement, HCFC-123 may turn out to be the most dangerous substitute. This chemical has been deemed so harmful that one of the largest chiller repair companies in the world, Johnson Controls Inc., announced last July that it would not allow any of its maintenance people to work with any equipment that uses HCFC-123. This decision was attacked by producers of HCFC-123 manufacturing plants. Johnson Controls stood its ground, pointing to the toxicological evidence. The company's decision follows that of most European countries to ban HCFC-123. European manufacturers first discovered that it turns into poisonous gas when subject to high temperatures. DuPont., the biggest maker of HCFC-123, has refused to halt production, saying that it ensures safety by not selling the chemical to companies that will use it for foam blowing, as a solvent for cleaning electronic components, or in dry cleaning. The question is: how will DuPont control resale of HCFC-123 by independent distributors? The problems of HCFC-123 do not end there, however. This CFC replacement has been proven to cause tumors in rats. Where's the testing? In addition to all this, the toxicity studies have serious shortcomings. The Program for Alternative Fluorocarbon Toxicity Testing (PAFT), the chemical industry consortium that conducted the tests, has not addressed the issue of human exposure. Although toxicity studies on rats are useful, they cannot replace studies of what these chemicals do to humans in real situations. Not to have examined the actual effect on human beings is unconscionable, especially given the number of people exposed to these chemicals. There are more than 600,000 service personnel in the U.S. alone who work with all types of cooling and refrigeration systems. Even if PAFT had carried out the necessary human exposure studies, there would still be many questions regarding its long-term effects. It may be 15 years before the carcinogenic effects of SUVA and other replacement chemicals start showing up in service personnel. Furthermore, there has been no testing for synergistic effects of these chemicals. As toxicologists know, two harmless chemicals may become toxic or carcinogenic when combined. Therefore, before high-exposure chemicals are released to commercial use, there usually is at least some testing for synergistic effects. This situation was denounced by refrigeration expert Eli Lieberman. In Air Conditioning, Heating and Refrigeration News, he warns "the problem is greatly complicated in that the refrigeration service engineer will now be exposed to a whole family of newly synthesized refrigerants in addition to the CFCs presently in use. No toxicity testing has been done on the possible synergistic toxic effect of breathing eight to 10 different refrigerants at the workplace over a period of time." From a moral standpoint, it is outrageous that no synergistic toxicity testing has been conducted. From a legal standpoint, it may be criminal. The 1976 Toxic Substances Control Act (TSCA) mandates that before any new chemical is introduced into commerce, it should undergo testing for "cumulative or synergistic effects." In its zeal to ban CFCs, the EPA has turned a blind eye to possible synergistic toxic effects and also failed to enforce other TSCA requirements. As a matter of fact, EPA itself is violating the law. Reva Rubenstein, the EPA official in charge of toxicity studies, has refused to release any of these studies to the public. Even industry officials who design and manufacture equipment that uses CFC substitutes have been unable to obtain these studies. Ms. Rubenstein has told some callers that "these studies may confuse you." A product manager for a large auto manufacturer reports that he told her his company needed to obtain the studies because it was liable for any harm caused by SUVA emitted from its cars. "That's your problem, not ours," Ms. Rubenstein replied. EPA's refusal to provide these studies to the public raises many questions, notably "What are they trying to hide?" There must be some serious issues the EPA is trying to conceal, because refusal to provide these toxicity studies carries not only severe civil penalties under TSCA, but is considered a criminal act. Worldwide, the total price tag for banning so-called ozone depleters could run to $5 trillion. The question remains, however, does the unproven threat of ozone depletion warrant all the expensive steps being taken? RETHINKING THE LAW Faced with differing opinions among the scientific community on whether CFCs really deplete the ozone layer and the looming costs of the CFC ban, legislators are reconsidering the U.S. position. Some politicians feel that the government was panicked into a rash decision to accelerate the phaseout and soon will pay the price for that hasty decision. Some legislators want an airing of the current evidence for and against the CFC ozone-depletion theory so that they can make up their minds on what to do about the currently scheduled CFC phaseout. In August 1992, for example, Rep. William Dannemeyer (R-Calif.) sponsored House Resolution 547 to establish a special presidential commission to review the scientific evidence surrounding ozone depletion and CFCs. It would have been made up of scientists and experts from both sides of the issue. Scientists who contend that manmade CFCs have no effect on the ozone layer, ultraviolet radiation reaching the earth's surface, or the incidence of cancer were excluded from previous review panels. NASA's Ozone Trends Panel, for example, was supervised and directed solely by backers of the CFC ozone-depletion theory. Last October, Rep. John Doolitle (R-Calif.) reintroduced Dannemeyer's bill in Congress. Hearings on this bill, HR-291, are scheduled for February. THE RECYCLING BOONDOGGLE Recycling plays a central role in the strategy of those promoting the CFC ban. They assert that more than 30% of all the CFCs still needed after production is banned will come from recycling. This is unlikely, for after two years of mandated recovery and recycling, the amount recovered is negligible. One problem is that the machinery needed to carry out this mandate is expensive, priced from $1,500 to $50,000, and that does not include installation, filters, and maintenance, or the cost of training and certifying operators. Maintenance personnel must use a recovery/recycling unit whenever servicing CFC-using equipment, with a separate unit needed for each refrigeration gas recovered. Mixing gases damages the recycling unit and the mixed gases become expensive to dispose of legally. Shop owners who do not use these units risk hefty fines and jail time. Complying with government mandates will require an estimated 375,000 recycling units. That number may double since these fragile machines require constant maintenance. And because shops cannot do business without an operational unit, many will buy three units, two for R-12 and one for R-134a. Another drawback is that when maintenance workers are called to service a unit because it is no longer cooling, most of the refrigerant has already escaped. To comply with the law, maintenance personnel will have to evacuate empty systems. The only CFCs actually recoverable is the temporary charge used to pinpoint leaks and determine necessary repairs, or when a perfectly operating system is emptied prior to being dismantled. Reusing what few CFCs can be recycled may not be smart, anyway. Improperly recycled CFCs can contaminate and damage expensive air-conditioning equipment. The only analysis methods capable of determining the purity of recovered CFCs are gas chromatography, nuclear magnetic resonance, and chemical analysis, and these cost between $100 and $300 per sample. For all of these reasons, the calculations on the amount of CFCs available from recovery are vast overestimates. Rogelio A. (Roger) Maduro has written articles on earth and atmospheric sciences, the environment and environmental law, and new developments in industrial technologies. He studied civil engineering at Washington University, St. Louis, and earned a bachelor of science in geology from City College of New York. He also authored the book The Holes in the Ozone Scare: The Scientific Evidence that the Sky is Not Falling. Bob Holzknecht owned and operated an auto-air repair shop for 25 years and formed a trade association, Automotive Air Group, of similar businesspersons. He also edited The Accumulator, a monthly technical newsletter covering automotive air conditioning issues. He now serves as the founder and organizer of the Ozone Truth Squad, an organization aimed at countering the one-sided version of the CFC/ozone depletion theory. Source Citation (MLA 8th Edition) Maduro, Rogelio A., and Bob Holzknecht. "The $5 trillion mistake." Machine Design, 24 Jan. 1994, p. 53+.
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